Espectroscopia de fotoelétrons de limiares do ozônio e do CCI4

Abstract

This work registered for the first time the valence shell threshold photoelectron spectrum of ozone and CCl4. In the O3 spectrum, acquired in the energy range from 12 eV to 21 eV, we observed, in contrast with previous published PE spectra from literature, a vibrational progression of regular spacing to the band system 1 2A1. Furthermore, we noted that the formation of the ionic states 2 2B1, 3 2A1, 4 2B2 is favored by indirect ionization processes due to the strong contribution of vibronic coupling, resulting in a non-adiabatic behavior. Extensive vibrational structures were observed in the ionic state 2 2B1 of ozone. In the study of CCl4 molecule between 12 to 25 eV, important differences were observed between the obtained TPE spectrum and early registered PE spectra from other authors. The presence of additional bands in TPE spectrum was interpreted as resonances between a neutral excited state of CCl4 molecule with ionic states of fragments. With basis on this interpretation the kinetic energy of some fragments were calculated.