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dc.creatorGraúdo, José Eugênio Jesus Cardoso-
dc.creatorFilgueiras, Carlos A. L.-
dc.creatorMarques-Netto, Antonio-
dc.creatorBatista, Alzir A.-
dc.date.accessioned2019-02-22T13:23:24Z-
dc.date.available2019-02-21-
dc.date.available2019-02-22T13:23:24Z-
dc.date.issued2000-06-
dc.citation.volume11pt_BR
dc.citation.issue3pt_BR
dc.citation.spage237pt_BR
dc.citation.epage240pt_BR
dc.identifier.doihttp://dx.doi.org/10.1590/S0103-50532000000300006pt_BR
dc.identifier.urihttps://repositorio.ufjf.br/jspui/handle/ufjf/9167-
dc.description.abstractA series of six ferrocene derivatives containing a semicarbazone or thiosemicarbazone side chain was investigated by cyclic voltammetry and positron annihilation lifetime measurements. Both the redox and the electron capture processes took place on the Fe atom. Correlations between the two methods were proposed, taking into account the substituents on the side chain of the compounds, their redox potentials and the probabilities of o-positronium (o-Ps).formation.pt_BR
dc.description.resumoUma série de seis derivados de ferroceno contendo uma cadeia lateral de semicarbazona ou tiossemicarbazona foi investigada por voltametria cíclica e estudos utilizando medidas de tempo de vida de pósitrons. Ambos os fenômenos, tanto o processo redox como o de captura de elétrons, ocorreram no átomo de ferro. Foram propostas correlações entre os dois métodos, levando em conta os substituintes na cadeia lateral dos compostos, os potenciais redox e as probabilidades de formação de o-positrônio (o-Ps).pt_BR
dc.languageengpt_BR
dc.publisher-pt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.initials-pt_BR
dc.relation.ispartofJournal of the Brazilian Chemical Societypt_BR
dc.rightsAcesso Abertopt_BR
dc.subjectSemicarbazonept_BR
dc.subjectThiosemicarbazonept_BR
dc.subjectFerrocenept_BR
dc.subjectCyclic voltammetrypt_BR
dc.subjectPositronium formationpt_BR
dc.subject.cnpq-pt_BR
dc.titleElectrochemical and positron annihilation studies of semicarbazones and thiosemicarbazones derived from ferrocenept_BR
dc.typeArtigo de Periódicopt_BR
Appears in Collections:Artigos de Periódicos



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